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Regioselective biomimetic oxidation of etodolac with iodosylbenzene catalyzed by halogenated and perhalogenated metalloporphyrins in dichloromethane

Chemical and Pharmaceutical Bulletin (2001) 49(10) 1375-1376
DOI: 10.1248/cpb.49.1375
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Abstract

The biomimetic oxidation of etodolac, an anti-inflammatory drug (1)with iodosylbenzene catalyzed by 5,10,15,20-tetraarylporphyrinatoiron(III) chlorides TAPFe(III)Cl (7a - e) in dichloromethane gives 4-hydroxyetodolac (6) and 4-oxoetodolac (5) regioselectively in moderate yields.

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Chauhan, S. M. S., Kandadai, S. A., & Sahoo, B. (2001). Regioselective biomimetic oxidation of etodolac with iodosylbenzene catalyzed by halogenated and perhalogenated metalloporphyrins in dichloromethane. Chemical and Pharmaceutical Bulletin, 49(10), 1375–1376. https://doi.org/10.1248/cpb.49.1375

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