Abstract
The enantioselective intermolecular gold-(I)-catalyzed [2+2] cycloaddition of terminal alkynes and alkenes has been achieved using non-C2-chiral Josiphos digold(I) complexes as catalysts, by the formation of the monocationic complex. This new approach has been applied to the enantioselective total synthesis of rumphellaone A.
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CITATION STYLE
APA
García-Morales, C., Ranieri, B., Escofet, I., López-Suarez, L., Obradors, C., Konovalov, A. I., & Echavarren, A. M. (2017). Enantioselective synthesis of cyclobutenes by intermolecular [2+2] cycloaddition with non-c2 symmetric digold catalysts. Journal of the American Chemical Society, 139(39), 13628–13631. https://doi.org/10.1021/jacs.7b07651
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