Effect of sodium phosphate and calcium nitrate sealing treatment on microstructure and corrosion resistance of wire arc sprayed aluminum coatings

Abstract

Aluminum coating was deposited by arc thermal spraying process onto the steel substrate for the corrosion protection in aggressive environment. However, the arc thermal sprayed coating possesses defects in the coating. Thus, it is important to reduce the defects and enhance the corrosion resistance properties of the deposited coating using post-treatment. In the present study, we have used different concentrations of sodium phosphate mono basic (NaH2PO4) with 0.1 molar (M) calcium nitrate [Ca(NO3)2] as post-treatment solution to fill out the defects of the Al coating. It was observed by scanning electron microscopy (SEM) that 1MNaH2PO4 with 0.1MCa(NO3)2 treated sample exhibited 71% reduction in defects compared to as coated samples. X-ray di_raction (XRD) was performed to determine the phases formed on the coating surface after treatments. XRD confirms the formation of sodium aluminum hydrogen phosphate (Na3Al(OH)(HPO4)(PO4) and brushite (Ca(HPO4)(H2O) 2) as composite oxides on the Al coating. Electrochemical results show that 0.5 M NaH2PO4 with 0.1 M Ca(NO3)2 treated sample has exhibited the highest charge transfer resistance and the lowest corrosion current density after 89 days of exposure in 3.5 wt. % NaCl solution. The enhancement in corrosion resistance of 0.5 M NaH2PO4 with 0.1 M Ca(NO3)2 treated sample attributed to the formation of adherent, sparingly soluble, and stable corrosion products. The volume fraction result of the corrosion products formed on 0.5 M NaH2PO4 with 0.1 M Ca(NO3)2 treated sample after 89 days of exposure in 3.5 wt. % NaCl using XRD confirms the highest amount of Bayerite (α-Al(OH) 3) deposition, thus, the corrosion rate of this sample was the lowest.