Abstract
The advantages of heterogeneous catalysis and transition-metal catalysis in ionic liquids are combined in rhodium bisphosphine catalysts in an ionic-liquid phase on a silica support. These active, regioselective, and highly stable catalysts were applied in a fixed-bed reactor for the continuous-flow gas-phase hydroformylation of propene.
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Riisager, A., Fehrmann, R., Flicker, S., Van Hal, R., Haumann, M., & Wasserscheid, P. (2005). Very stable and highly regioselective supported ionic-liquid-phase (SILP) catalysis: Continuous-flow fixed-bed hydroformylation of propene. Angewandte Chemie - International Edition, 44(5), 815–819. https://doi.org/10.1002/anie.200461534
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