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α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis

Angewandte Chemie - International Edition (2016) 55(1) 254-258
DOI: 10.1002/anie.201506147
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Abstract

Direct access to complex, enantiopure benzylamine architectures using a synergistic iridium photoredox/nickel cross-coupling dual catalysis strategy has been developed. New C(sp3)-C(sp2) bonds are forged starting from abundant and inexpensive natural amino acids.

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El Khatib, M., Serafim, R. A. M., & Molander, G. A. (2016). α-Arylation/Heteroarylation of Chiral α-Aminomethyltrifluoroborates by Synergistic Iridium Photoredox/Nickel Cross-Coupling Catalysis. Angewandte Chemie - International Edition, 55(1), 254–258. https://doi.org/10.1002/anie.201506147

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