Abstract
A copper iodide complex coordinated by three phosphine ligands with the formula [Cu2I2(Ph2PC2(C6H4)C2PPh2)3] exhibits solvatochromic and vapochromic luminescence properties. A mechanism based on solvent-dependent molecular motion appears to occur. The highly contrasted response observed upon THF solvent exposure makes this complex an appealing candidate for chemical sensor applications.
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Benito, Q., Balogh, C. M., El Moll, H., Gacoin, T., Cordier, M., Rakhmatullin, A., … Perruchas, S. (2018). Luminescence Vapochromism of a Dynamic Copper Iodide Mesocate. Chemistry - A European Journal, 24(71), 18868–18872. https://doi.org/10.1002/chem.201804377
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