Co-incorporation of hydrotalcite and starch into biochar-based fertilizers for the synthesis of slow-release fertilizers with improved water retention

Abstract

The unsatisfactory nutrient slow-release and water-retention performance of traditional biochar-based compound fertilizers (BCF) severely limit their practical application. Herein, a new type of slow-release fertilizer with high water retention was fabricated via the incorporation of hydrotalcite and starch into BCF, named as HS-BCF. The water-retention and nutrient releasing performance of the prepared HS-BCF and related nutrient slow-release mechanism were investigated. The results showed that the incorporation of hydrotalcite and starch into BCF could increase the soil water-retention ratio by 5–10% points. The accumulated N, P, and K leaching amounts of HS-BCF in soil within 30 days were 49.4%, 13.3%, and 87.4% of BCF at most, respectively. Kinetic analysis indicated that the release of nutrients from HS-BCF was attributed to the coupling of the diffusion-controlled and relaxation-controlled mechanism. Moreover, hydrotalcite could bind with P in HS-BCF, contributing to the enhanced durability of P in HS-BCF. Finally, pot experiments showed that the N–P–K utilization efficiencies of HS-BCF were all higher than those of BCF due to a better synchronization between the nutrient release of HS-BCF and the uptake of tomato plants. Overall, the study may provide a promising strategy for simultaneously improving the water-retention and slow-release performance of traditional biochar-based fertilizers. Graphical Abstract: [Figure not available: see fulltext.]