Ion selective electrodes are not suitable for measurements of silver ion concentrations in alkaline carbonate media

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Abstract

An ion selective electrode (ISE) for determination of the labile silver ion concentration in carbonate containing solutions of pH 10 was seen to give incorrect results due to shifts in the Ag|Ag+ equilibrium. This drawback was not the case for the differential pulse anodic stripping voltammetry (DPASV) method. © 2013 The Royal Society of Chemistry.

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Hedberg, J., Lowe, T. A., Wold, S., & Odnevall Wallinder, I. (2013). Ion selective electrodes are not suitable for measurements of silver ion concentrations in alkaline carbonate media. Analytical Methods, 5(4), 1068–1070. https://doi.org/10.1039/c2ay26300a

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