Electron transfer from Zn-Protoporphyrin IX to ruthenium ammine attached at His63 of reconstituted cytochrome b562

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Abstract

Site-specific modification of Cytochrome b562 with ruthenium ammine (RuA5) at 63-His was successfully carried out. Electron transfer rate from ZnPP in the heme crevice to Ru(III)A5 coordinated to 63-His on the protein surface was determined by the laser flash photolysis.

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Hamachi, I., Takashima, H., Tsukiji, S., Shinkai, S., Nagamune, T., & Oishi, S. (1999). Electron transfer from Zn-Protoporphyrin IX to ruthenium ammine attached at His63 of reconstituted cytochrome b562. Chemistry Letters, (7), 551–552. https://doi.org/10.1246/cl.1999.551

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