Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding

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Abstract

The molecular conformation of a bis-helicenic terpyridine system is strongly modified upon binding to Zn(ii) ion, a process that is accompanied by large changes in the optical and chiroptical properties. This system affords a new type of helicene-based chiroptical switching.

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Isla, H., Srebro-Hooper, M., Jean, M., Vanthuyne, N., Roisnel, T., Lunkley, J. L., … Crassous, J. (2016). Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding. Chemical Communications, 52(35), 5932–5935. https://doi.org/10.1039/c6cc01748g

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