Multifunctional Performance of Sodiated Carbon Fibers

Abstract

An investigation is conducted into the potential for sodiated PAN-based carbon fibers (CFs) to be used in multifunctional actuation, sensing, and energy harvesting. Axial CF expansion/contraction is measured during sodiation/desodiation using operando strain measurements. The reversible expansion/contraction is found to be 0.1% — which is lower than that of lithiated CFs. The axial sodiation expansion occurs in two well-defined stages, corresponding to the sloping and plateau regions of the galvanostatic cycling curve. The results indicate that the sloping region most likely corresponds to sodium insertion between graphitic sheets, while the plateau region corresponds to sodium insertion in micropores. A voltage-strain coupling is found for the CFs, with a maximum coupling factor of 0.15 ± 0.01 V/unit strain, which could be used for strain sensing in multifunctional structures. This voltage-strain coupling is too small to be exploited for harvesting mechanical energy. The measured axial expansion is further used to estimate the capacity loss due to solid electrolyte interphase (SEI) formation, as well as capacity loss due to sodium trapped in the CF microstructure. The outcomes of this research suggest that sodiated CFs show some potential for use as actuators and sensors in future multifunctional structures, but that lithiated CFs show more promise.