Abstract
The complex [Cu(xantphos)(dmp)][PF6] (dmp = 2,9-dimethyl-1,10-phenanthroline) in a nanostructured metal oxyde matrix shows better sensitivity to oxygen (KSV = 9.74 ± 0.87 kPa-1 between 0 and 1 kPa pO2 and 5.59 ± 0.15 kPa-1 between 0 and 10 kPa pO2) than cyclometallated iridium complexes in the same conditions.
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APA
Medina-Rodríguez, S., Orriach-Fernández, F. J., Poole, C., Kumar, P., De La Torre-Vega, Á., Fernández-Sánchez, J. F., … Fernández-Gutiérrez, A. (2015). Copper(i) complexes as alternatives to iridium(iii) complexes for highly efficient oxygen sensing. Chemical Communications, 51(57), 11401–11404. https://doi.org/10.1039/c5cc04326c
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