Diethyl 2-{[2-(trifluoromethyl)anilino]methyl-idene}propanedioate

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Abstract

The title compound, C 15H 16F 3NO 4, is an N-substituted derivative of ortho-trifluoro-methyl-aniline featuring a twofold Michael system. The least-squares planes defined by the atoms of the phenyl ring and the atoms of the Michael system enclose an angle of 15.52 (5)°. Apart from classical intra-molecular N - H⋯O and N - H⋯F hydrogen bonds, inter-molecular C - H⋯O contacts are observed, the latter connecting the mol-ecules into chains along [110]. The shortest inter-centroid distance between two aromatic systems is 3.6875 (9) Å.

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Garudachari, B., Isloor, A. M., Satyanarayan, M. N., Gerber, T., Hosten, E., & Betz, R. (2012). Diethyl 2-{[2-(trifluoromethyl)anilino]methyl-idene}propanedioate. Acta Crystallographica Section E: Structure Reports Online, 68(2). https://doi.org/10.1107/S1600536812002590

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