Highly branched photomechanical crystals

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Abstract

When a suspension of the tert-butyl ester of 4-fluoroanthracene-9-carboxylic acid (4F9AC) was slowly hydrolyzed, highly branched photomechanical microcrystals of 4F9AC were grown. Exposure to UV light caused the branches to undergo a reversible sweeping motion that could be used to move and concentrate silica microspheres on a surface.

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Al-Kaysi, R. O., Tong, F., Al-Haidar, M., Zhu, L., & Bardeen, C. J. (2017). Highly branched photomechanical crystals. Chemical Communications, 53(17), 2622–2625. https://doi.org/10.1039/C6CC08999B

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