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Palladium-catalyzed dimerization of meso-bromoporphyrins: highly regioselective meso-bβ coupling through unprecedented remote C-H bond cleavage

Chemistry - A European Journal (2009) 15(45) 12208-12211
DOI: 10.1002/chem.200902143
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Abstract

Linked porphyrins: A porphyrin undergoes unique homocoupling in the reaction of meso-bromoporphyrins under palladium catalysis (see scheme). Formal remote C - H bond cleavage leads directly to the construction of meso-Bβ-linked diporphyrins in good yields with perfect regioselectivity. © 2009 wiley-VCH Verlag GmbH & Co. KGaA,.

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Tokuji, S., Yurino, T., Aratani, N., Shinokubo, H., & Osuka, A. (2009). Palladium-catalyzed dimerization of meso-bromoporphyrins: highly regioselective meso-bβ coupling through unprecedented remote C-H bond cleavage. Chemistry - A European Journal, 15(45), 12208–12211. https://doi.org/10.1002/chem.200902143

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