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Nucleophilic Displacement Catalyzed by Transition Metal. IX. [Pd2(dba)3]·CHCl3–DPPF Catalyzed Cyanation of Aryl Halides and Aryl Triflates

  • Takagi K
  • Sasaki K
  • Sakakibara Y
Bulletin of the Chemical Society of Japan (1991) 64(4) 1118-1121
DOI: 10.1246/bcsj.64.1118
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Abstract

A catalyst system comprising [Pd2(dba)3]·CHCl3 and DPPF was proved to be efficient for the cyanation of aryl iodides and aryl triflates with KCN. The reactivities of aryl substrates decreased in the order ArI>ArOTf>ArBr.

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Takagi, K., Sasaki, K., & Sakakibara, Y. (1991). Nucleophilic Displacement Catalyzed by Transition Metal. IX. [Pd2(dba)3]·CHCl3–DPPF Catalyzed Cyanation of Aryl Halides and Aryl Triflates. Bulletin of the Chemical Society of Japan, 64(4), 1118–1121. https://doi.org/10.1246/bcsj.64.1118

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