Crystal structure of diethyl 3,3′-{2,2′-(1 E)-[1,4-phenylenebis(azan-1-yl-1-yl-idene)]bis(methan-1-yl-1-ylidene) bis(1 H-pyrrole-2,1-diyl)}dipropanoate

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Abstract

The complete molecule of the title compound, C26H30N4O4, is generated by crystallographic inversion symmetry. The dihedral angle between the planes of the benzene and pyrrole rings is 45.20 (11)°; the N atom bonded to the the benzene ring and the pyrrole N atom are in a syn conformation. The side chain adopts an extended conformation [N - C - C - C = 169.07 (17)° and C - O - C - C = - 176.54 (17)°]. No directional interactions could be identified in the crystal packing.

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Alshawi, J., Yousif, M., Timco, G., Yrezabal, I. J. V., Winpenny, R., Al-Jeboori, M. J., & Harrison, W. T. A. (2015). Crystal structure of diethyl 3,3′-{2,2′-(1 E)-[1,4-phenylenebis(azan-1-yl-1-yl-idene)]bis(methan-1-yl-1-ylidene) bis(1 H-pyrrole-2,1-diyl)}dipropanoate. Acta Crystallographica Section E: Structure Reports Online, 71(4), o259–o260. https://doi.org/10.1107/S2056989015005113

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