UiO66-Derived Catalyst for Low Temperature Catalytic Reduction of NO with NH3

Abstract

Diesel exhaust emissions are major outdoor air pollutants. Reducing the emission of NOx by diesel commercial vehicles and related machineries is at present a great challenge. In this study, we synthesize a catalyst for low-temperature catalytic reduction of NO using calcinated UiO-66(Zr) as a host for the doping of cerium, manganese, and titanium by the incipient wetness impregnation, followed by the dispersion of 1.0 wt % platinum. A solid solution of Ce0.15Zr0.54Mn0.11Ti0.20O2/1.0Pt (CZMTO/Pt) is synthesized as evident by the structural characterizations. The catalyst demonstrates significant NO reduction in the laboratory due to the synergistic effect of various elements, with NO conversion above 80% at 160 °C.