Kinetics and mechanism of NaOH-impregnated calcined oyster shell-catalyzed transesterification of soybean oil

Abstract

The objective of this research is to develop a kinetic model to describe the transesterification of soybean oil with methanol using NaOH-impregnated calcined oyster shell (Na-COS). Batch experiments were performed via a two-factor randomized complete block design using a molar ratio of methanol to oil (MR) of 6, 12, and 18 and catalyst loadings (CL) (mass of catalyst/mass of oil in %) of 2%, 4%, 6%, and 8% to obtain fatty acid methyl ester yields. In addition, the catalyst was studied by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion spectrometry (TOF-SIMS) to elucidate the role of the catalyst in the transesterification reaction. XRD and XPS analyses suggested that the formation of sodium peroxide (Na2O2) on the surface contributed to catalytic activity. The TOF-SIMS analysis suggested that the transesterification occurred between adsorbed triglyceride and free methanol, similar to the Eley-Rideal mechanism. The transesterification of adsorbed triglyceride to adsorbed diglyceride was found to be the rate-determining step with a rate constant of 0.0059 ± 0.0002 L mol-1 min-1.