Bromido(dodecafluorosubphthalo-cyaninato)boron(III)

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Abstract

The title compound, C24BBrF12N6 or Br-F12BsubPc (BsubPc is boronsubphtalocyanine), has a bowl-shaped structure with an approximate mol-ecular C 3v symmetry characteristic of boronsubphthalocyanine compounds. In the crystal, molecules are arranged in one-dimensional columns and the boron-subphthalocyanine units within each column are offset and angled in a bowl-to-ligand packing arrangement such that the axial Br atom rests in the aromatic concaved bowl of the neighboring subphthalocyanine with an inter-molecular Br⋯B distance of 3.721 (3) Å.

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Morse, G. E., Maka, J. F., Lough, A. J., & Bender, T. P. (2010). Bromido(dodecafluorosubphthalo-cyaninato)boron(III). Acta Crystallographica Section E: Structure Reports Online, 66(12). https://doi.org/10.1107/S1600536810041863

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