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Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal-Ligand Cooperation

ACS Catalysis (2018) 8(9) 8014-8019
DOI: 10.1021/acscatal.8b02902
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Abstract

Deoxygenative hydrogenation of amides to amines homogeneously catalyzed by a complex of an Earth-abundant metal is presented. This manganese-catalyzed reaction features high efficiency and selectivity. A plausible reaction mechanism, involving metal-ligand cooperation of the manganese pincer complex, is proposed based on NMR studies and relevant stoichiometric reactions.

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Zou, Y. Q., Chakraborty, S., Nerush, A., Oren, D., Diskin-Posner, Y., Ben-David, Y., & Milstein, D. (2018). Highly Selective, Efficient Deoxygenative Hydrogenation of Amides Catalyzed by a Manganese Pincer Complex via Metal-Ligand Cooperation. ACS Catalysis, 8(9), 8014–8019. https://doi.org/10.1021/acscatal.8b02902

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