Review—Polymer Electrolytes for Magnesium Batteries: Forging Away from Analogs of Lithium Polymer Electrolytes and Towards the Rechargeable Magnesium Metal Polymer Battery

Abstract

Batteries based on alternatives to lithium are now of global research interest. Magnesium metal batteries are particularly attractive for their potential high energy density. Polymer electrolytes for high density rechargeable batteries have been sought for decades, due to their improved thermal stability compared with liquids and their lower density and cost compared with inorganic solids. Yet, little success has so far been realized in polymer electrolytes for magnesium metal batteries. In this review, the magnesium polymer electrolyte literature is comprehensively explored. Differences between requirements for lithium polymer and magnesium polymer batteries are discussed as well as the consequences on necessary considerations for impactful magnesium polymer electrolyte research.