Abstract
A sumanene-based aryne "sumanyne" was generated from o-(trifluoromethylsulfonyloxy)sumanenyl pinacolatoborane with CsF under microwave irradiation. Formation of a sumanyne intermediate was confirmed by a reaction with diene compounds to afford the Diels-Alder adducts, and its structure was determined by single-crystal X-ray structure analysis.
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APA
Ngamsomprasert, N., Yakiyama, Y., & Sakurai, H. (2017). A sumanene-based aryne, “Sumanyne.” Chemistry Letters, 46(4), 446–448. https://doi.org/10.1246/cl.161117
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