Electrochemical rearrangement protocols towards the construction of diverse molecular frameworks

Abstract

Rearrangement reactions constitute a critical facet of synthetic organic chemistry and demonstrate an attractive way to take advantage of existing structures to access various important molecular frameworks. Electroorganic chemistry has emerged as an environmentally benign approach to carry out organic transformations by directly employing an electric current and avoids the use of stoichiometric chemical oxidants. The last few years have witnessed a resurgence of electroorganic chemistry that has promoted a renaissance of interest in the development of novel redox electroorganic transformations. This review manifests the evolution of electrosynthesis in the area of rearrangement chemistry and covers the achievements in the field of migration, ring expansion, and rearrangements along with the mechanisms involved.