Herein we report the synthesis of a zeolitic imidazolate framework (ZIF-8) by an easy “mix and wait” procedure. In a closed vial, without any interference, the mixture of 2-methylimidazole and basic zinc carbonate assembles into the crystalline product with approx. 90% conversion after 70 h. The reaction exhibits sigmoidal kinetics due to the self-generated water which accelerates the reaction.
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CITATION STYLE
Gugin, N., Villajos, J. A., Feldmann, I., & Emmerling, F. (2022). Mix and wait - a relaxed way for synthesizing ZIF-8. RSC Advances, 12(15), 8940–8944. https://doi.org/10.1039/d2ra00740a