Supra-molecular assembly of aromatic proton sponges to direct the crystallization of extra-large-pore zeotypes

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Abstract

The combination of different experimental techniques, such as solid 13Cand1Hmagic-angle spinning NMR spectroscopy, fluorescence spectroscopy and powder X-ray diffraction, together with theoretical calculations allows the determination of the unique structure directing the role of the bulky aromatic proton sponge 1,8-bis(dimethylamino)naphthalene (DMAN) towards the extra-large-pore ITQ-51 zeolite through supra-molecular assemblies of those organic molecules. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

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Martinez-Franco, R., Sun, J., Sastre, G., Yun, Y., Zou, X., Moliner, M., & Corma, A. (2014). Supra-molecular assembly of aromatic proton sponges to direct the crystallization of extra-large-pore zeotypes. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, 470(2166). https://doi.org/10.1098/rspa.2014.0107

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