An introduction to stratospheric chemistry: Survey article

Abstract

This paper is an expansion of the lectures presented by the authors at the Canadian Middle Atmosphere Model (CMAM) summer school, 25–29 August 1997. It attempts to fulfill several goals as did the curriculum for the summer school. Firstly, it has a large tutorial component allowing newcomers a rapid introduction to the field, secondly it surveys the field of stratospheric chemistry, and thirdly it attempts to bring the reader to the forefront of some of the problem areas in stratospheric chemistry. As such, it includes much background information such as the magnitude of rate coefficients, photolysis rates and their calculation and time constants. The intended audience is individuals about to commence study or research in the field of atmospheric chemistry or established atmospheric scientists in other areas wishing to expand their knowledge of this topic. The basic chemistry of the ozone layer is described with an emphasis on the catalytic cycles and the equilibria between “reservoir” and “active” species. To this end, a compendium of the important aspects of heterogeneous chemistry is also provided. The application of box (0-dimensional) and more elaborate (1-, 2- and 3-dimensional) models to compare and validate with measurements is discussed. Also, factors affecting the present and future trends in ozone concentration, both at mid-latitudes and in the polar region, are presented. © 1999 Taylor & Francis Group, LLC.