Adsorption Behaviour of Pyrazolo [3, 4-b] Pyridine on Corrosion of Stainless Steel in HCl Solutions

  • James O
  • Ajanaku K
  • Ogunniran K
  • et al.
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Abstract

The properties of stainless steel makes the alloy suitable for many application; but this tends to change at very aggressive conditions thereby making its properties to fail. The corrosion inhibition efficiency of 2-(4-Methyl-3-oxo-2-phenyl-2, 3-dihydro-1H-pyrazolo [3, 4-b] pyridin-4-yl) acetic acid butylester (PP) on stainless steel in HCl solution was studied by weight loss method. The adsorption mechanism was investigated using adsorption isotherms. The experimental data fit Flory-Huggins and Thermodynamic/El-Awady models. The values for free energy of adsorption, ΔGoads, of PP at different surface coverage, θ, were also calculated by applying the mathematical model of Bockris-Swinkels adsorption isotherm. The variation of free energy of adsorption ΔGoads.with surface coverage, θ, was rationalised in term of interaction between adsorbed PP molecules. A possible adsorption model of PP molecules on to the steel surface was suggested.

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James, O. O., Ajanaku, K. O., Ogunniran, K. O., Ajani, O. O., Siyanbola, T. O., & John, M. O. (2011). Adsorption Behaviour of Pyrazolo [3, 4-b] Pyridine on Corrosion of Stainless Steel in HCl Solutions. Trends in Applied Sciences Research, 6(8), 910–917. https://doi.org/10.3923/tasr.2011.910.917

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