Synthesis and optical spectroscopy of Na3Y(VO4)2:Eu3+ phosphors for thermometry and display applications

Abstract

A new Na3Y(VO4)2:Eu3+(NYVO:Eu3+) phosphor was prepared using the sol-gel method. X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to evaluate phase purity and particle size, respectively. The optical properties were investigated by UV-visible absorption, PL, and PLE spectroscopies. The absorption measurements show the formation of the vanadate host by the presence of its characteristic band in the visible region related to VO43-groups. The experimental results show that the NYVO:Eu3+phosphors exhibit high-brightness and thermally stable emission. Under near-ultraviolet (UV) excitation, both the broadband emission from VO43-groups and the sharp peak emissions from Eu3+ions are observed. The highest luminescence intensity was achieved for an optimal europium concentration of 15 mol%. The study of the chromaticity parameters of these compounds gives a thermally stable hot emission in the red domain, with a color purity of about 85%, which qualifies the NYVO:Eu3+compound as a potential phosphor for light-emitting diode (LED) applications. Thermal sensing using NYVO:Eu3+phosphors are based on monitoring the luminescence intensity ratio between the NYVO host emission and Eu3+luminescence lines. Notably, the optical thermometry of NYVO:Eu3+was characterized based on the fluorescence intensity ratio of VO43-and Eu3+emissions in the 298-440 K range, with maximum absolute and relative sensitivities of 3.4% K-1and 0.0032 K-1respectively and a temperature uncertainty of 0.01. NYVO:Eu3+can then be considered as a potential red phosphor for application in ultraviolet-pumped white light-emitting diodes and as a potential optical thermometer. It provides new possibilities for the design of multifunctional materials for red light-emitting diodes and for non-contact thermometry.