Photocatalytic Performance of Organically Templated Cr-Doped Co3O4 in Remediation of Industrial Wastewater: Effect of Order–Disorder in the Lattice

Abstract

In photocatalysis, the optical properties and surface parameters significantly affect the catalytic performance. To engineer the optical properties and textural structure, Cr and p-phenylene diamine (PDA) were utilized as dopant and textural structure regulator, respectively. A series of Cr-doped Co3O4 with dopant percentages of 0, 1, 3, and 5, templated PDA at a fixed ratio of 5%, and another un-templated sample with a dopant ratio of 5% were prepared. The co-precipitation method was applied in swift and innovative procedures, where a calculated amount of NaOH was used as a precipitant. The optical properties, dopant concentration quenching, and surface parameters are strongly affected by the order–disorder in the lattice and dopant concentration. The lattice regularity affects the optical properties and the surface parameters along with the dopant concentration. The photocatalysts were evaluated in the disposal of organic pollutants in a representative sample of wastewater collected from different industrial activities. The function of another function was applied to monitor the pollutants' disposal, taking the total organic carbon (TOC) as a function of the pollutants' concentration and the photometric absorbance as a function of the TOC. The kinetic investigation exhibited the significant role of the pore system on the reaction rate.