Short communication: Inverse isochron regression for Re-Os, K-Ca and other chronometers

Abstract

Conventional Re-Os isochrons are based on mass spectrometric estimates of 187Re/188Os and 187Os/188Os, which often exhibit strong error correlations that may obscure potentially important geological complexity. Using an approach that is widely accepted in 40Ar/39Ar and U-Pb geochronology, we here show that these error correlations are greatly reduced by applying a simple change of variables, using 187Os as a common denominator. Plotting 188Os/187Os vs. 187Re/187Os produces an "inverse isochron", defining a binary mixing line between an inherited Os component whose 188Os/187Os ratio is given by the vertical intercept, and the radiogenic 187Re/187Os ratio, which corresponds to the horizontal intercept. Inverse isochrons facilitate the identification of outliers and other sources of data dispersion. They can also be applied to other geochronometers such as the K-Ca method and (with less dramatic results) the Rb-Sr, Sm-Nd and Lu-Hf methods. Conventional and inverse isochron ages are similar for precise datasets but may significantly diverge for imprecise ones. A semi-synthetic data simulation indicates that, in the latter case, the inverse isochron age is more accurate. The generalised inverse isochron method has been added to the IsoplotR toolbox for geochronology, which automatically converts conventional isochron ratios into inverse ratios, and vice versa.