Preparation of spherical nanocomposites consisting of silica core and polyacrylate shell by emulsion polymerization

Abstract

Nanocomposite particles consisting of silica (inorganic core) and polyacrylate (organic shell) were prepared in a form of emulsion by a new and simple method - the emulsion polymerization of acrylic monomers in the presence of silica sol. The key technique of the present emulsion polymerization, which made the formation of the nanocomposites successful, is the usage of nonionic surfactant above its cloud point. The morphology of the composite was investigated by DLS, AFM, and TEM, which clearly showed formation of the core-shell-type particles. A transparent film was prepared by casting the emulsion, which showed high resistitiility against organic solvents. © 2005 Wiley Periodicals, Inc.