Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide

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Abstract

Herein we report the synthesis and characterisation of a series of Zr(IV) 2,2′-bipyrrolidine-salan derived complexes and their exploitation for the ring opening polymerisation of rac-lactide to afford highly isotactically enriched polymers. © The Royal Society of Chemistry 2014.

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Jones, M. D., Hancock, S. L., McKeown, P., Schäfer, P. M., Buchard, A., Thomas, L. H., … Lowe, J. P. (2014). Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide. Chemical Communications, 50(100), 15967–15970. https://doi.org/10.1039/c4cc07871c

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