Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes

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Abstract

The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

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Shephard, A. C. G., Daniels, D. P., Deacon, G. B., Guo, Z., Jaroschik, F., & Junk, P. C. (2022). Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes. Chemical Communications, 58(27), 4344–4347. https://doi.org/10.1039/d2cc00698g

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