Interpretation of Raman spectra of disordered and amorphous carbon

Abstract

The model and theoretical understanding of the Raman spectra in disordered and amorphous carbon are given. The nature of the G and D vibration modes in graphite is analyzed in terms of the resonant excitation of π states and the long-range polarizability of π bonding. Visible Raman data on disordered, amorphous, and diamondlike carbon are classified in a three-stage model to show the factors that control the position, intensity, and widths of the G and D peaks. It is shown that the visible Raman spectra depend formally on the configuration of the (Formula presented) sites in (Formula presented)-bonded clusters. In cases where the (Formula presented) clustering is controlled by the (Formula presented) fraction, such as in as-deposited tetrahedral amorphous carbon (ta-C) or hydrogenated amorphous carbon (a-C:H) films, the visible Raman parameters can be used to derive the (Formula presented) fraction. © 2000 The American Physical Society.