Anthracene-fused BODIPYs as near-infrared dyes with high photostability

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Abstract

An anthracene unit was successfully fused to the zigzag edge of a boron dipyrromethene (BODIPY) core by an FeCl 3-mediated oxidative cyclodehydrogenation reaction. Meanwhile, a dimer was also formed by both intramolecular cyclization and intermolecular coupling. The anthracene-fused BODIPY monomer 7a and dimer 7b showed small energy gaps (∼1.4 eV) and near-infrared absorption/emission. Moreover, they exhibited high photostability. © 2011 American Chemical Society.

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Zeng, L., Jiao, C., Huang, X., Huang, K. W., Chin, W. S., & Wu, J. (2011). Anthracene-fused BODIPYs as near-infrared dyes with high photostability. Organic Letters, 13(22), 6026–6029. https://doi.org/10.1021/ol202493c

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