Comparative estimation of nitrogen in urea and its derivative products using TKN, CHNS and hand-held refractometer

Abstract

In this paper, a comparative analysis between the hand-held refractometer and other methods (TKN and CHNS) was accomplished for the estimation of nitrogen percentage (N%) in urea, nano urea fertilizer, and diesel exhaust fluid (DEF) solution. In order to compare the performance of all methods/devices, the detection of N% in different concentrations of urea, nano urea, and DEF were evaluated in terms of their linearity. The most important finding of this study was that the refractometer-based device revealed a good linear coefficient up to 40% urea solution (R2 = 0.99918) among other approaches, which means the estimation of N% is more close to the theoretical value. Moreover, the refractometer has detected the urea, nano urea, and DEF samples within 3 s which were quite fast as compared to other tested methods and no requirement of any chemicals during the sample preparation and analyses. Thus, the finding of this study suggests that a hand-held urea refractometer-based portable device can be used for onsite N% determination by the fertilizer and DEF manufacturing industries and their customers due to its low cost, low power requirement, reliable estimation, rapid N% detection, and its environmental suitability.