Stabilization of a superconducting TbSr2Cu2.85Re 0.15O7+δ compound and the valence state of terbium

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Abstract

A single-phase Sr-based Tb-123 phase has been synthesized by chemical stabilization. TbSr2Cu2.85Re0.15O 7+δ exhibits superconductivity at Tc,zero=22 K. X-ray diffraction results suggest a relatively small orthorhombicity and neutron diffraction studies indicate an excess oxygen content (≥7.2) in the sample. Tb is present as a trivalent ion in the superconducting phase as derived from x-ray photoelectron spectroscopy.© 1995 American Institute of Physics.

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Murugesan, M., Selvam, P., Sharon, M., Rao, M. S. R., Gupta, L. C., Pinto, R., … Subramanian, S. (1995). Stabilization of a superconducting TbSr2Cu2.85Re 0.15O7+δ compound and the valence state of terbium. Applied Physics Letters, 67, 2711. https://doi.org/10.1063/1.114301

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