Synthesis of furanoid and pyranoid C-1 aryl glycals by reaction of glycosyl chlorides with organolithium reagents

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Abstract

Furanosyl and pyranosyl chlorides react with aryllithium derivatives, obtained by directed ortho-lithiation of activated arenes, to give C-1 aryl glycals in moderate yields.

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Gömez, A. M., Casillas, M., Rodríguez, B., Valverde, S., & Löpez, J. C. (2010). Synthesis of furanoid and pyranoid C-1 aryl glycals by reaction of glycosyl chlorides with organolithium reagents. Arkivoc, 2010(3), 288–302. https://doi.org/10.3998/ark.5550190.0011.324

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