Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change

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Abstract

The synthesis, and magnetic and photoluminescence investigations of two bifunctional dysprosium complexes based on tridentate Schiff base ligands is reported. Magnetic investigations reveal a genuine single-molecule magnet (SMM) behavior, with out-of-phase signals up to 60 K, and tunable emission arising from the Schiff base ligands.

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Long, J., Basalov, I. V., Forosenko, N. V., Lyssenko, K. A., Mamontova, E., Cherkasov, A. V., … Trifonov, A. A. (2019). Dysprosium Single-Molecule Magnets with Bulky Schiff Base Ligands: Modification of the Slow Relaxation of the Magnetization by Substituent Change. Chemistry - A European Journal, 25(2), 474–478. https://doi.org/10.1002/chem.201804429

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