Magnetite Nanoparticles Synthesized Using Grape Fruit Extract: Synthesis, Morphology, Hyperthermia Application and Catalytic Activity in Hydrogen Peroxide Decomposition

Abstract

The paper presents a simple one-step "green" approach to the synthesis of magnetite nanoparticles. The magnetite nanoparticles were synthesized using fruit extract obtained from grape peels and grape pulp. The formation of magnetite nanoparticles was confirmed by X-ray diffraction analysis (XRD), infrared spectroscopy (IR), Mössbauer spectroscopy, scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The crystallites sizes of magnetite nanoparticles are 7 and 14 nm for Fe3O4-peel and Fe3O4-pulp samples, respectively. Scanning electron microscopy images show that the samples consist of agglomerated nanoparticles. The synthesized magnetite nanoparticles showed good prospects for their use in magnetic hyperthermia. SAR values of 0.488 W/g and 1.330 W/g for Fe3O4-peel and Fe3O4-pulp samples, respectively. The maximum hyperthermia temperatures are 42.28 °C and 42.48 °C for Fe3O4-peel and Fe3O4-pulp samples, respectively. Studies of the catalytic activity of magnetite were performed in decomposition of hydrogen peroxide in a batch mode. The high catalytic activity of the synthesized samples makes them promising candidates for the decomposition of hydrogen peroxide in wastewater disinfection.