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Probing Redox Non-Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance

Angewandte Chemie - International Edition (2021) 60(52) 27220-27224
DOI: 10.1002/anie.202110704
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Abstract

We report the synthesis and spectroscopic characterization of a series of iron-carbene complexes in redox states {Fe=C(H)Ar}10–11. Pulse EPR studies of the 1,2H and 13C isotopologues of {Fe=C(H)Ar}11 reveal the high covalency of the Fe–carbene bonding, leading to a more even spin distribution than commonly observed for reduced Fischer carbenes.

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Arnett, C. H., Oyala, P. H., & Agapie, T. (2021). Probing Redox Non-Innocence in Iron–Carbene Complexes {Fe=C(H)Ar}10–11 by 1,2H and 13C Pulse Electron Paramagnetic Resonance. Angewandte Chemie - International Edition, 60(52), 27220–27224. https://doi.org/10.1002/anie.202110704

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