A series of isoreticular, highly stable, porous zirconium oxide based metal-organic frameworks

Abstract

Brolly good MOFs: A new series of hydrophobic isoreticular porous Zr oxide dicarboxylate MOFs have been prepared (see picture, Zr blue polyhedra, O red, C black). They have a one-dimensional pore system, a rare combination of Lewis acidity and hydrophobic character, and a higher hydrothermal and mechanical stability than their UiO MOF polymorph counterparts. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.