N-(tert-Butoxycarbonyl)-N-[4-(dimethylazaniumylidene)-1,4-dihydropyridin-1- ylsulfonyl]azanide: A new sulfamoylating agent. Structure and reactivity toward amines

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Abstract

(Matrix presented) Synthesis, structure, and reactivity toward amines of the new sulfamoylating reagent 2 are described. Compound 2 allowed sulfamoylation of amines under very mild conditions to give sulfamide derivatives in good yields.

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Winum, J. Y., Toupet, L., Barragan, V., Dewynter, G., & Montero, J. L. (2001). N-(tert-Butoxycarbonyl)-N-[4-(dimethylazaniumylidene)-1,4-dihydropyridin-1- ylsulfonyl]azanide: A new sulfamoylating agent. Structure and reactivity toward amines. Organic Letters, 3(14), 2241–2243. https://doi.org/10.1021/ol0161312

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