Electrochemical recycling of polymeric materials

Abstract

Polymeric materials play a pivotal role in our modern world, offering a diverse range of applications. However, they have been designed with end-properties in mind over recyclability, leading to a crisis in their waste management. The recent emergence of electrochemical recycling methodologies for polymeric materials provides new perspectives on closing their life cycle, and to a larger extent, the plastic loop by transforming plastic waste into monomers, building blocks, or new polymers. In this context, we summarize electrochemical strategies developed for the recovery of building blocks, the functionalization of polymer chains as well as paired electrolysis and discuss how they can make an impact on plastic recycling, especially compared to traditional thermochemical approaches. Additionally, we explore potential directions that could revolutionize research in electrochemical plastic recycling, addressing associated challenges.