Ni/Mn metal–organic framework decorated bacterial cellulose (Ni/Mn-MOF@BC) and nickel foam (Ni/Mn-MOF@NF) as a visible-light photocatalyst and supercapacitive electrode

Abstract

Recently, metal–organic frameworks (MOFs) and hybrids with biomaterial are broadly investigated for a variety of applications. In this work, a novel dual-phase MOF has been grown on bacterial cellulose (BC) as a biopolymer nano-fibrous film (Ni/Mn-MOF@BC), and nickel foam (Ni/Mn-MOF@NF) using a simple reflux method to explore their potential for photocatalyst and energy storage applications. The studies showed that the prepared Mn and Ni/Mn-MOFs display different structures. Besides, the growth of MOFs on BC substantially changed the morphology of the samples by reducing their micro sized scales to nanoparticles. The nanosized MOF particles grown on BC served as a visible-light photocatalytic material. Regarding the high surface area of BC and the synergistic effect of two metal ions, Ni/Mn-MOF@BC with a lower band gap demonstrates remarkable photocatalytic degradation efficiency (ca. 84% within 3 h) against methylene blue (MB) dye under visible light, and the catalyst retained 65% of its initial pollutant removal properties after four cycles of irradiation. Besides, MOF powders deposited on nickel foam have been utilized as highly capacitive electrochemical electrodes. There, Ni/Mn-MOF@NF electrode also possesses outstanding electrochemical properties, showing a specific capacitance of 2769 Fg−1 at 0.5 Ag−1, and capacity retention of 94% after 1000 cycles at 10 Ag−1.