Abstract
(Chemical Equation Presented) Oxidation without organics: A tetraruthenium polyoxometalate (see picture; Ru blue, O red, Si yellow, W black) catalyzes the rapid oxidation of H2O to O2 in water at ambient temperature, and shows considerable stability under turnover conditions. The complex was characterized by several methods, including X-ray crystallography and cyclic voltammetry. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Geletii, Y. V., Botar, B., Kögerler, P., Hillesheim, D. A., Musaev, D. G., & Hill, C. L. (2008). An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation. Angewandte Chemie - International Edition, 47(21), 3896–3899. https://doi.org/10.1002/anie.200705652
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