Fluorescent garlic-capped Ag nanoparticles as dual sensors for the detection of acetone and acrylamide

Abstract

In order to protect human health from the adverse impacts of acrylamide and acetone, simple analytical processes are required to detect low concentrations of acrylamide and acetone. Dual functional garlic-capped silver nanoparticles (G-Ag NPs) have been used as fluorescent sensors for acrylamide and acetone. This technique depends on the quenching of the photoluminescence (PL) intensity of G-Ag NPs with the interaction of either acrylamide or acetone. This fluorescent probe presented high selectivity toward acrylamide with a wide linear response of 0.01-6 mM with a limit of detection (LOD) of 2.9 μM. Moreover, this probe also acted as a selective and sensitive fluorescent sensor for the detection of acetone in the range of 0.1-17 mM with LOD of 55 μM. The applicability of G-Ag NPs as a proposed sensor for acrylamide was evaluated using a potato chips sample with a recovery percentage of 102.4%. Acetone concentration is also quantified in human urine samples and the recoveries ranged from 98.8 to 101.7%. Repeatability and reproducibility studies for acrylamide and acetone offered relative standard deviation (RSD) of 0.9% and 1.5%, and 0.77% and 1.1%, respectively.