Directed synthesis of {Mn18Cu6} heterometallic complexes

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Abstract

A two-step method for the directed synthesis of high-nuclearity Mn III-MnII-CuII heterometallic transition metal complexes is described. The synthesis starts from a preformed copper(II) complex to trap an inner hexacapped cuboctahedral manganese oxide core. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Milway, V. A., Tuna, F., Farrell, A. R., Sharp, L. E., Parsons, S., & Murrie, M. (2013). Directed synthesis of {Mn18Cu6} heterometallic complexes. Angewandte Chemie - International Edition, 52(7), 1949–1952. https://doi.org/10.1002/anie.201208781

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