Barley agro-industrial residues as corrosion inhibitor for mild steel in 1mol L-1 HCl solution

Abstract

The corrosion inhibition of mild steel in 1 mol L-1 HCl by barley grains and malting process residue extracts was investigated by weight loss measurements, polarization curves, electrochemical impedance measurements and scanning electron microscopy. The inhibition efficiency exceeded 92% in the presence of 100 mg L-1 extracts after 24 h immersion time for both extracts. The Ea decreased with the addition of the extracts, characterizing the chemical adsorption by the molecules present in the extracts on the surface. The high molecular weight fraction isolated from the barley grain extract also showed high inhibition efficiency, suggesting that macromolecules are probably responsible for the inhibitory action.